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• W2038835966 abstract "Redox behavior of indenyl sandwich complexes of general formula (η5-C9H7)ML (M = Ru and L = η5- C9H7 (bdI), η5-C5H5 (II), η5-C5Me5 (III); M = Os, L = η5-C9H7 (IV)) has been studied by means of cyclic voltammetry at the Pt-electrode at −85–20°C in THF, MeCN and CH2 Cl2. The title complexes have been found to undergo reversible one-electron oxidation to corresponding radical cations, whose stability and reactivity depend on the nature of both a metal and the second aromatic π-ligand L and nucleophilic properties of the solvent. Fast reversible interaction of the electrogenerated 17-electron radical cations with nucleophiles yields bent sandwich 19-electron radical cations, [(η5-C9H7)M(Nu)L]+.(Nu = Cl−, MeCN, THF), the latter undergo one-electron oxidation to corresponding 18-electron [(η5-C9H7)M(Nu)L]2+ dications." @default.
• W2038835966 created "2016-06-24" @default.
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• W2038835966 date "1996-07-01" @default.
• W2038835966 modified "2023-10-16" @default.
• W2038835966 title "Reactivity of 17- and 19-electron organometallic complexes.Formation of bent sandwich 19-electron radical cation complexes of osmium and ruthenium" @default.
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• W2038835966 doi "https://doi.org/10.1016/0022-328x(95)06102-9" @default.
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