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- W2038844186 abstract "The reaction of 1,4-dilithiotetraphenylbutadiene with excess vinyltrichlorosilane produces both the 1,2,3,4-tetraphenyl-6-dichlorovinylsilyl-5-dichlorosilacyclohepta-1,3-diene (1) and its oligomer (2). The precipitation of 2 in methanol yields its dimethoxy derivative (3). The dimethyl (4) and diphenyl (5) derivatives of 2 are obtained in good yields by reacting 1,4-dilithiotetraphenylbutadiene with excess chlorodimethylvinylsilane and chlorodiphenylvinylsilane, respectively, without forming their respective monomer. In contrast, the reaction of 1,4-dilithiotetraphenylbutadiene with excess allyltrichlorosilane grves 1-allyl-1-chloro-2,3,4,5-tetraphenylsilole only." @default.
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- W2038844186 date "2000-05-01" @default.
- W2038844186 modified "2023-10-14" @default.
- W2038844186 title "Serendipitous Synthesis of Oligo(6-vinylsilyl-5-silacyclohepta-1,3-diene)s" @default.
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- W2038844186 doi "https://doi.org/10.1246/cl.2000.544" @default.
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