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- W2038851971 abstract "Abstract Vnylpyridinium salts based on 4-, 2- and 2-methyl-5-vinylpyridines containing different alkylating agents polymerize rapidly in aqueous solutions if the monomeric salt concentrations are high enough (3 mole/l. or more). The reactive centres of this polymerization are of an anionic (zwitterion) character, as opposed to radical reactive centres, in view of the fact that copolymerization with acrylic acid fails to take place, and the monomer structure precludes cationic initiation. Cu 2+ ions do not inhibit the reaction, but CO 2 does. No spontaneous polymerization at all was observed with dilute solutions of the vinylpyridinium salts (less than 1 mole/l.), but it may be initiated by free pyridine or vinylpyridine additions to the reaction mixture. An analysis of the zwitterion polymerization of vinylpyridine quaternary salts leads to the conclusion that an extremely important role is played by ionic associates that appear in fairly concentrated aqueous solutions." @default.
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- W2038851971 date "1975-01-01" @default.
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- W2038851971 title "Mechanism of the polymerization of vinylpyridinium salts in aqueous solutions" @default.
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