FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2038852011> ?p ?o ?g. }

• W2038852011 endingPage "430" @default.
• W2038852011 startingPage "423" @default.
• W2038852011 abstract "Comprehension of short- and medium-range order of phosphate glasses is a topic of interest, due to the close relation between network structure and mechanical, thermal, and optical properties. In this work, the short-range structure of glasses (1 - x)Ca(PO(3))(2).xAl(PO(3))(3) with 0 < or = x < or = 0.47 was studied using solid-state nuclear magnetic resonance spectroscopy, Raman spectroscopy, density measurements, and differential scanning calorimetry. The bonding between a network modifier species, Al, and the network forming phosphate groups was probed using high-resolution nuclear magnetic resonance spectroscopy of (27)Al and (31)P. Changes in the compositional behavior of the density, glass transition temperature, PO(2) symmetric vibrations, and Al coordination number were verified at around x = 0.30. (31)P NMR spectra show the presence of phosphorus in Q(2) sites with nonbridging oxygens (NBOs) coordinated by Ca ions and also Q(2) sites with one NBO coordinated by Al (namely, Q(2)(1Al)). The changes in the properties as a function of x can be understood by considering the mean coordination number measured for Al and the formation of only Q(2) and Q(2)(1Al) species. It is possible to calculate that a network formed only by Q(2)(1Al) phosphates can just exist up to the upper limit of x = 0.48. Above this value, Q(2)(2Al) species should appear, imposing a major reorganization of the network. Above x = 0.30 the network undergoes a progressive reorganization to incorporate Al ions, maintaining the condition that only Q(2)(1Al) species are formed. These observations support the idea that bonding principles for cationic species inferred originally in binary phosphate glasses can also be extended to ternary systems." @default.
• W2038852011 created "2016-06-24" @default.
• W2038852011 creator A5023443174 @default.
• W2038852011 creator A5032971429 @default.
• W2038852011 creator A5056717881 @default.
• W2038852011 creator A5075506505 @default.
• W2038852011 creator A5084088738 @default.
• W2038852011 date "2004-12-30" @default.
• W2038852011 modified "2023-10-18" @default.
• W2038852011 title "Short-Range Structure and Cation Bonding in Calcium−Aluminum Metaphosphate Glasses" @default.
• W2038852011 cites W1966504731 @default.
• W2038852011 cites W1968146012 @default.
• W2038852011 cites W1983157362 @default.
• W2038852011 cites W1992952922 @default.
• W2038852011 cites W1994381312 @default.
• W2038852011 cites W1996552900 @default.
• W2038852011 cites W2010719723 @default.
• W2038852011 cites W2021005016 @default.
• W2038852011 cites W2064390258 @default.
• W2038852011 cites W2066432383 @default.
• W2038852011 cites W2072171238 @default.
• W2038852011 cites W2075220663 @default.
• W2038852011 cites W2081154921 @default.
• W2038852011 cites W2112086768 @default.
• W2038852011 cites W2160806999 @default.
• W2038852011 cites W2161501934 @default.
• W2038852011 cites W2570656372 @default.
• W2038852011 cites W2953130956 @default.
• W2038852011 doi "https://doi.org/10.1021/ic0499704" @default.
• W2038852011 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/15651890" @default.
• W2038852011 hasPublicationYear "2004" @default.
• W2038852011 type Work @default.
• W2038852011 sameAs 2038852011 @default.
• W2038852011 citedByCount "29" @default.
• W2038852011 countsByYear W20388520112012 @default.
• W2038852011 countsByYear W20388520112013 @default.
• W2038852011 countsByYear W20388520112014 @default.
• W2038852011 countsByYear W20388520112016 @default.
• W2038852011 countsByYear W20388520112018 @default.
• W2038852011 countsByYear W20388520112019 @default.
• W2038852011 countsByYear W20388520112020 @default.
• W2038852011 countsByYear W20388520112021 @default.
• W2038852011 countsByYear W20388520112022 @default.
• W2038852011 countsByYear W20388520112023 @default.
• W2038852011 crossrefType "journal-article" @default.
• W2038852011 hasAuthorship W2038852011A5023443174 @default.
• W2038852011 hasAuthorship W2038852011A5032971429 @default.
• W2038852011 hasAuthorship W2038852011A5056717881 @default.
• W2038852011 hasAuthorship W2038852011A5075506505 @default.
• W2038852011 hasAuthorship W2038852011A5084088738 @default.
• W2038852011 hasConcept C113196181 @default.
• W2038852011 hasConcept C120665830 @default.
• W2038852011 hasConcept C121332964 @default.
• W2038852011 hasConcept C122865956 @default.
• W2038852011 hasConcept C130188946 @default.
• W2038852011 hasConcept C145148216 @default.
• W2038852011 hasConcept C147597530 @default.
• W2038852011 hasConcept C152365726 @default.
• W2038852011 hasConcept C153642686 @default.
• W2038852011 hasConcept C178790620 @default.
• W2038852011 hasConcept C185592680 @default.
• W2038852011 hasConcept C2776335861 @default.
• W2038852011 hasConcept C2777132085 @default.
• W2038852011 hasConcept C2781094431 @default.
• W2038852011 hasConcept C32891209 @default.
• W2038852011 hasConcept C33559828 @default.
• W2038852011 hasConcept C39519442 @default.
• W2038852011 hasConcept C40003534 @default.
• W2038852011 hasConcept C43617362 @default.
• W2038852011 hasConcept C521977710 @default.
• W2038852011 hasConcept C62520636 @default.
• W2038852011 hasConcept C66974803 @default.
• W2038852011 hasConcept C71240020 @default.
• W2038852011 hasConcept C8010536 @default.
• W2038852011 hasConcept C97355855 @default.
• W2038852011 hasConceptScore W2038852011C113196181 @default.
• W2038852011 hasConceptScore W2038852011C120665830 @default.
• W2038852011 hasConceptScore W2038852011C121332964 @default.
• W2038852011 hasConceptScore W2038852011C122865956 @default.
• W2038852011 hasConceptScore W2038852011C130188946 @default.
• W2038852011 hasConceptScore W2038852011C145148216 @default.
• W2038852011 hasConceptScore W2038852011C147597530 @default.
• W2038852011 hasConceptScore W2038852011C152365726 @default.
• W2038852011 hasConceptScore W2038852011C153642686 @default.
• W2038852011 hasConceptScore W2038852011C178790620 @default.
• W2038852011 hasConceptScore W2038852011C185592680 @default.
• W2038852011 hasConceptScore W2038852011C2776335861 @default.
• W2038852011 hasConceptScore W2038852011C2777132085 @default.
• W2038852011 hasConceptScore W2038852011C2781094431 @default.
• W2038852011 hasConceptScore W2038852011C32891209 @default.
• W2038852011 hasConceptScore W2038852011C33559828 @default.
• W2038852011 hasConceptScore W2038852011C39519442 @default.
• W2038852011 hasConceptScore W2038852011C40003534 @default.
• W2038852011 hasConceptScore W2038852011C43617362 @default.
• W2038852011 hasConceptScore W2038852011C521977710 @default.
• W2038852011 hasConceptScore W2038852011C62520636 @default.
• W2038852011 hasConceptScore W2038852011C66974803 @default.
• W2038852011 hasConceptScore W2038852011C71240020 @default.

• next