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- W2038860080 abstract "NbX5 (X = F, 1a; X = Cl, 1b) reacted with γ-butyrolactone (but), ε-caprolactam (cap), δ-valerolactam (val) in 1:1 M ratio in chlorinated solvent, affording either the neutral coordination adducts NbCl5L (L = but, 2a; L = val, 2b) or the ionic ones [NbX4L2][NbX6] (X = F, L = but, 3a; X = F, L = val, 3b; X = F, L = cap, 3c; X = Cl, L = cap, 3d). The reaction of 1a with equimolar amount of guanine (gua) in CH3CN resulted in the formation of the complex [NbF4(gua)2][NbF6], 3e. The addition of two equivalents of organic substrate to 1 gave selectively the compounds NbCl5L2 (L = but, 4a; L = val, 4b) or [NbF4L4][NbF6] (L = but, 5a; L = val, 5b; L = cap, 5c). The 1:2 M reaction of 1b with ε-caprolactam proceeded with C–N bond activation and afforded the derivative , 6, in high yield." @default.
- W2038860080 created "2016-06-24" @default.
- W2038860080 creator A5053942420 @default.
- W2038860080 creator A5062096538 @default.
- W2038860080 date "2011-10-01" @default.
- W2038860080 modified "2023-09-23" @default.
- W2038860080 title "The reactivity of NbX5 (X=F, Cl) with lactons, lactams, and the synthesis of the first nucleobase-containing niobium complex" @default.
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- W2038860080 doi "https://doi.org/10.1016/j.ica.2011.06.006" @default.
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