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- W2038861344 abstract "A complex of samarium diiodide (SmI(2)) with tetraglyme catalyzes the intermolecular pinacol coupling of aromatic or aliphatic aldehydes at loadings of 10 mol % in the presence of Me(2)SiCl(2) and Mg. Diastereoselectivity of up to 95/5 (+/-/meso) has been achieved for aliphatic aldehydes and up to 19/81 (+/-/meso) for aromatic aldehydes. De values of up to 99% have been achieved in intramolecular pinacol coupling reactions using the SmI(2)/tetraglyme/Mg/Me(2)SiCl(2) catalytic system." @default.
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- W2038861344 date "2005-04-09" @default.
- W2038861344 modified "2023-09-30" @default.
- W2038861344 title "Samarium Diiodide-Catalyzed Diastereoselective Pinacol Couplings" @default.
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- W2038861344 doi "https://doi.org/10.1021/ol050256f" @default.
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