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- W2038863152 abstract "This paper reports the synthesis and complete characterization (structural, spectroscopic and magnetic) of [Cu(HBIMAM)Cl(C4O4)]n · (H2O)n [BIMAM = bis(imidazol-2-yl)methylaminomethane]. This compound is made of infinite chains – running along c axis – built from [CuCl(HBIMAM)]+ units bridged together by μ-O1,O3-bis(monodentate) squarate anions. Non-covalent interactions (H-bonds and π–π) drive the build-up of an infinite three-dimensional array. The coordination polyhedron about the copper(II) ion is distorted square pyramidal. The EPR spectrum is indicative of a dz2-y2 ground state for the Cu(II) ions with significant contribution of dz2. Magnetic susceptibility measurements in the range 1.8–200 K show weak antiferromagnetic exchange interactions (2J = −3.5(1) cm−1). The observed magnetic behaviour is discussed in terms of the crystal structure and compared with that observed in related copper(II) complexes containing μ-O1,O3-squarato bridges." @default.
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- W2038863152 date "2006-07-01" @default.
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- W2038863152 title "Structure, spectroscopic and magnetic properties of a novel 1-D coordination copper(II) polymer containing BIMAM ligand [BIMAM=bis(imidazol-2-yl)methylaminomethane] and μ-1,3 squarato bridges" @default.
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- W2038863152 doi "https://doi.org/10.1016/j.ica.2006.03.039" @default.
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