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- W2038863531 abstract "The hydrogen bonding interactions between thioacetamide (TA) and several N,N-disubstituted benzamides (N,N-dimethylbenzamide (DMBA), N-methoxy-N-methylbenzamide (MMBA), N,N-diethyl-m-toluamide (DEMT), and N,N-diethyl-2,5-difluorobenzamide (DEDF)) have been studied using near-infrared absorption spectroscopy. Thermodynamic parameters for the interactions between TA and benzamides were determined by analyzing the νN-Has + amide II combination band of TA. The −ΔH0 values, indicating the intrinsic strength of hydrogen bonding, are −17.4, −21.6, −21.9 and −20.8 kJ mol−1 for DMBA, MMBA, DEMT and DEDF, respectively. The results show that the inductive and resonance effects of substituents appear to influence the formation of hydrogen bonds." @default.
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- W2038863531 date "1996-11-01" @default.
- W2038863531 modified "2023-09-23" @default.
- W2038863531 title "Near-infrared spectroscopic studies of the hydrogen bonding between thioacetamide and N,N-disubstituted benzamide derivatives in CCl4" @default.
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- W2038863531 doi "https://doi.org/10.1016/s0584-8539(96)01715-1" @default.
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