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• W2038864069 abstract "The sensitization mechanisms of ketocoumarin dyes with a radical-generating reagent, 10,10′-carbonylbis[1,1,7,7-tetramethyl-2,3,6,7-tetrahydro-1H,5H,11H-[1]benzopyrano[6,7,8-ij]quinolizin-11-one] (KCD-J), 7,7′-bis(diethylamino)-3,3′-carbonyldicoumarin (KCD-DA) with 3,3′,4,4′-tetrakis(t-butyldioxycarbonyl)benzophenone (I) in poly(methyl methacrylate) film containing dimethyl phthalate (DMP) as a plasticizer have been investigated by laser flash photolysis using a total reflection cell. The fluorescence of the dyes was efficiently quenched by I in PMMA containing 50 wt% of DMP (film A) against total solid with static quenching distances of 12.5 and 12.7 A for KCD-J and KCD-DA. The static quenching distance was around 1.5 times longer than that in PMMA. The decay time of the triplet in a film A was slightly quenched by I with a kq of less than 1.5 × 106 mol−1 dm3 s−1 for KCD-J and KCD-DA. These results show that a static singlet sensitization from the fluorescent excited dyes to I is the predominant process ..." @default.
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• W2038864069 date "1996-03-01" @default.
• W2038864069 modified "2023-09-26" @default.
• W2038864069 title "Laser Flash Photolysis in High-Speed Photopolymer Coating Layers: Effects of Incorporating Dimethyl Phthalate as a Plasticizer into Coating Formulation" @default.
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• W2038864069 doi "https://doi.org/10.1246/bcsj.69.693" @default.
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