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- W2038892162 abstract "This is the first reported work of artificial α-amanitin receptors which are prepared using the design and synthesis of a template molecule based on an α-amanitin recognition determinant imprinting strategy. The resultant molecularly imprinted polymers (MIPs) are evaluated using high performance liquid chromatography (HPLC), binding experiment, nitrogen adsorption measurement, and solid-phase extraction. Experiment clearly demonstrates that the MIPs as the HPLC stationary phase can specifically recognize α-amanitin from analogues. The MIPs also successfully adsorb trace amounts of α-amanitin in spiked serum samples selectively pretreated and enriched through molecularly imprinted solid phase extraction. The limit of detection and recovery is 3.0 ng mL(-1) and 88.5-95.9%, respectively, for α-amanitin in serum samples. The high specific adsorption and excellent selectivity of the MIPs arises from imprinting effects related to the imprinting cavity of the polymeric matrix, the metal-coordination bond, and the hydrogen bond between the receptor and ligand." @default.
- W2038892162 created "2016-06-24" @default.
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- W2038892162 date "2014-01-01" @default.
- W2038892162 modified "2023-10-18" @default.
- W2038892162 title "An artificial receptor fabricated by target recognition determinant imprinting for selective capture of α-amanitin" @default.
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- W2038892162 doi "https://doi.org/10.1016/j.chroma.2013.11.042" @default.
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