Matches in SemOpenAlex for { <https://semopenalex.org/work/W2039001433> ?p ?o ?g. }
Showing items 1 to 88 of
88
with 100 items per page.
- W2039001433 endingPage "72" @default.
- W2039001433 startingPage "65" @default.
- W2039001433 abstract "The reactions of cyclohexene (Ch) and tetralin (T) in the pure liquid state and in their solutions in chlorobenzene were found to exhibit a strong dependence on the concentration of the catalyst VO(acac)2: a double maximum curve was observed in consequence of the presence of the catalyst in various forms as a result of its tendency to undergo aggregation. The monomer form of the catalyst below 10−4 M proved more active than the dimer (or oligomer) at higher concentrations. However, only a single maximum was observed when toluene was applied as solvent in place of chlorobenzene. In a closed reactor system, the oxidation of Ch produced Ch-OOH, Ch-O (epoxide) and Ch-ol, but Ch-one was never found. In the oxidation of T, T-OOH, T-ol and T-one were obtained. In some cases, the sum of the oxidation products was greater than might be expected from the measured O2 uptake, because of the disproportionation of T-OOH into O2 and T-ol. It was observed that the catalyst is able to interact with and is thereby activated by T. Consequently, the oxidation of T can start in the absence of a hydroperoxide initiator; this was not the case, however, in the oxidation of Ch. The ion-pair VO2+–aerosol-OT also exerted a catalytic effect, but with lower activity, and a double maximum was not produced on increase of the ion-pair concentration." @default.
- W2039001433 created "2016-06-24" @default.
- W2039001433 creator A5007862721 @default.
- W2039001433 creator A5049838733 @default.
- W2039001433 creator A5054286569 @default.
- W2039001433 date "2002-02-01" @default.
- W2039001433 modified "2023-10-17" @default.
- W2039001433 title "Oxidation of hydrocarbons by O2 in the presence of VO(acac)2 as catalyst" @default.
- W2039001433 cites W1549949278 @default.
- W2039001433 cites W1980545080 @default.
- W2039001433 cites W1986594272 @default.
- W2039001433 cites W2002905502 @default.
- W2039001433 cites W2008803025 @default.
- W2039001433 cites W2025403322 @default.
- W2039001433 cites W2033620660 @default.
- W2039001433 cites W2041882226 @default.
- W2039001433 cites W2047113343 @default.
- W2039001433 cites W2067721799 @default.
- W2039001433 cites W2084114004 @default.
- W2039001433 cites W2084944469 @default.
- W2039001433 cites W2111417211 @default.
- W2039001433 cites W2122296054 @default.
- W2039001433 cites W2140448811 @default.
- W2039001433 cites W2320220220 @default.
- W2039001433 cites W2320952831 @default.
- W2039001433 doi "https://doi.org/10.1016/s1381-1169(01)00393-4" @default.
- W2039001433 hasPublicationYear "2002" @default.
- W2039001433 type Work @default.
- W2039001433 sameAs 2039001433 @default.
- W2039001433 citedByCount "16" @default.
- W2039001433 countsByYear W20390014332012 @default.
- W2039001433 crossrefType "journal-article" @default.
- W2039001433 hasAuthorship W2039001433A5007862721 @default.
- W2039001433 hasAuthorship W2039001433A5049838733 @default.
- W2039001433 hasAuthorship W2039001433A5054286569 @default.
- W2039001433 hasConcept C155647269 @default.
- W2039001433 hasConcept C161790260 @default.
- W2039001433 hasConcept C166940927 @default.
- W2039001433 hasConcept C17365422 @default.
- W2039001433 hasConcept C178790620 @default.
- W2039001433 hasConcept C179104552 @default.
- W2039001433 hasConcept C185592680 @default.
- W2039001433 hasConcept C2776041390 @default.
- W2039001433 hasConcept C2778142098 @default.
- W2039001433 hasConcept C2778216191 @default.
- W2039001433 hasConcept C2779484182 @default.
- W2039001433 hasConcept C2779546866 @default.
- W2039001433 hasConcept C2780471494 @default.
- W2039001433 hasConcept C521977710 @default.
- W2039001433 hasConcept C75473681 @default.
- W2039001433 hasConcept C78030364 @default.
- W2039001433 hasConceptScore W2039001433C155647269 @default.
- W2039001433 hasConceptScore W2039001433C161790260 @default.
- W2039001433 hasConceptScore W2039001433C166940927 @default.
- W2039001433 hasConceptScore W2039001433C17365422 @default.
- W2039001433 hasConceptScore W2039001433C178790620 @default.
- W2039001433 hasConceptScore W2039001433C179104552 @default.
- W2039001433 hasConceptScore W2039001433C185592680 @default.
- W2039001433 hasConceptScore W2039001433C2776041390 @default.
- W2039001433 hasConceptScore W2039001433C2778142098 @default.
- W2039001433 hasConceptScore W2039001433C2778216191 @default.
- W2039001433 hasConceptScore W2039001433C2779484182 @default.
- W2039001433 hasConceptScore W2039001433C2779546866 @default.
- W2039001433 hasConceptScore W2039001433C2780471494 @default.
- W2039001433 hasConceptScore W2039001433C521977710 @default.
- W2039001433 hasConceptScore W2039001433C75473681 @default.
- W2039001433 hasConceptScore W2039001433C78030364 @default.
- W2039001433 hasIssue "1-2" @default.
- W2039001433 hasLocation W20390014331 @default.
- W2039001433 hasOpenAccess W2039001433 @default.
- W2039001433 hasPrimaryLocation W20390014331 @default.
- W2039001433 hasRelatedWork W1964317169 @default.
- W2039001433 hasRelatedWork W1989754194 @default.
- W2039001433 hasRelatedWork W2067149123 @default.
- W2039001433 hasRelatedWork W2171617139 @default.
- W2039001433 hasRelatedWork W2356953592 @default.
- W2039001433 hasRelatedWork W2378828093 @default.
- W2039001433 hasRelatedWork W2384584335 @default.
- W2039001433 hasRelatedWork W2549379729 @default.
- W2039001433 hasRelatedWork W2768671325 @default.
- W2039001433 hasRelatedWork W4233532829 @default.
- W2039001433 hasVolume "179" @default.
- W2039001433 isParatext "false" @default.
- W2039001433 isRetracted "false" @default.
- W2039001433 magId "2039001433" @default.
- W2039001433 workType "article" @default.