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- W2039002102 abstract "Low-scattering monomer miniemulsions have recently emerged as a suitable system for the development of efficient photopolymerization processes in dispersed media. Since their reactivity under UV exposure is strongly dependent on their optical properties, there is a strong interest to find simple analytical methods for studying absorption and scattering with ready-to-polymerize concentrated miniemulsions, while avoiding dilution. This paper focuses on three types of concentrated miniemulsions without photoinitiator (PI) and containing either a hydrophilic or hydrophobic PI. The application of the two-flux theory of Kubelka–Munk on these multiple scattering miniemulsions enables the determination of the scattering and absorption coefficients for different initial droplet sizes. These results show that reaction kinetics are strongly correlated with scattering efficiency. Below a threshold average diameter of ca. 150 nm, any decrease of droplet size diminishes the extent of scattering significantly, thus improving light penetration and the reaction rate. Additionally, a complementary dynamic study proves that the smallest miniemulsions are subjected to a decrease of scattering during irradiation. This result opens up interesting perspectives on the elucidation of the nucleation mechanism operating in a miniemulsion photopolymerization." @default.
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- W2039002102 date "2014-04-28" @default.
- W2039002102 modified "2023-09-30" @default.
- W2039002102 title "Absorption and Scattering in Concentrated Monomer Miniemulsions: Static and Dynamic Investigations" @default.
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- W2039002102 doi "https://doi.org/10.1002/macp.201400072" @default.
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