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- W2039017788 abstract "Cyclic voltammetric (CV) and chronoamperometric (CA) behaviors of 1,3,5-triphenylformazan (TPF), 3-(p-nitrophenyl)-1,5-diphenylformazan (PNF) and 3-(m-nitrophenyl)-1,5-diphenylformazan (MNF) were studied in dimethyl sulfoxide medium. TPF was found to give a single sharp cathodic CV peak corresponding to a gain of one-electron per molecule. The diffusion coefficient and the number of electrons transferred were calculated using the Baranski equation with the CV-data obtained by an ultramicroelectrode. Standard rate constants for the reduction were calculated by the Klingler-Kochi technique. The electrochemical data obtained support the mechanism proposed by Umemoto." @default.
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- W2039017788 date "2005-06-01" @default.
- W2039017788 modified "2023-10-18" @default.
- W2039017788 title "Electrochemical Investigation of 1,3,5-Triphenylformazan and Its Nitro Derivatives in Dimethyl Sulfoxide" @default.
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- W2039017788 doi "https://doi.org/10.2116/analsci.21.685" @default.
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