FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2039069462> ?p ?o ?g. }

• W2039069462 endingPage "44" @default.
• W2039069462 startingPage "35" @default.
• W2039069462 abstract "Three distinct coordination complexes, viz., [Co(imi)2(tmb)2] (1) [where imi = imidazole], {[Ni(tmb)2(H2O)3]·2H2O}n (2) and [Cu2(μ-tmb)4(CH3OH)2] (3), have been synthesized hydrothermally by the reactions of metal acetates, 2,4,6-trimethylbenzoic acid (Htmb) and with or without appropriate amine. The Ni analogue of 1 and the Co analogue of 2 have also been synthesized. X-ray single-crystal diffraction suggests that complex 1 represents discrete mononuclear species and complex 2 represents a 1D chain coordination polymer in which the Ni(II) ions are connected by the bridging water molecules. Complex 3 represents a neutral dinuclear complex. In 1, the central metal ions are associated by the carboxylate moiety and imidazole ligands, whereas the central metal atom is coordinated to the carboxylate moiety and the respective solvent molecules in 2 and 3. In 3, the four 2,4,6-trimethylbenzoate moieties act as a bridge connecting two copper (II) ions and the O atoms of methanol coordinate in an anti arrangement to form a square pyramidal geometry, with the methanol molecule at the apical position. In all the three structures the central metal atom sits on a crystallographic inversion centre. In all the cases, the coordination entities are further organized via hydrogen bonding interactions to generate multifarious supramolecular networks. Complexes 1, 2 and 3 have also been characterized by spectroscopic (UV/Vis and IR) and thermal analysis (TGA). In addition, the complexes were found to exhibit antimicrobial activity.The magnetic susceptibility measurements, measured from 8 to 300 K, revealed antiferromagnetic interactions between the Co(II) ions in compound 1 and the Ni(II) ions in 1a, respectively." @default.
• W2039069462 created "2016-06-24" @default.
• W2039069462 creator A5005497815 @default.
• W2039069462 creator A5024004543 @default.
• W2039069462 creator A5030280190 @default.
• W2039069462 creator A5039779316 @default.
• W2039069462 creator A5074113233 @default.
• W2039069462 date "2009-08-01" @default.
• W2039069462 modified "2023-09-25" @default.
• W2039069462 title "Self-assembly of three new coordination complexes: Formation of 2-D square grid, 1-D chain and tape structures" @default.
• W2039069462 cites W1539796472 @default.
• W2039069462 cites W161557697 @default.
• W2039069462 cites W1756260249 @default.
• W2039069462 cites W1965476260 @default.
• W2039069462 cites W1975165348 @default.
• W2039069462 cites W1978633893 @default.
• W2039069462 cites W1980044104 @default.
• W2039069462 cites W1981704948 @default.
• W2039069462 cites W1982414593 @default.
• W2039069462 cites W1987894030 @default.
• W2039069462 cites W1990918587 @default.
• W2039069462 cites W2003866350 @default.
• W2039069462 cites W2009191711 @default.
• W2039069462 cites W2018330396 @default.
• W2039069462 cites W2019232572 @default.
• W2039069462 cites W2020040838 @default.
• W2039069462 cites W2032842297 @default.
• W2039069462 cites W2034238744 @default.
• W2039069462 cites W2041114202 @default.
• W2039069462 cites W2045106032 @default.
• W2039069462 cites W2045404539 @default.
• W2039069462 cites W2051341669 @default.
• W2039069462 cites W2061785750 @default.
• W2039069462 cites W2065112923 @default.
• W2039069462 cites W2065144521 @default.
• W2039069462 cites W2066821455 @default.
• W2039069462 cites W2070809142 @default.
• W2039069462 cites W2079108392 @default.
• W2039069462 cites W2084620777 @default.
• W2039069462 cites W2086946028 @default.
• W2039069462 cites W2087007092 @default.
• W2039069462 cites W2087221183 @default.
• W2039069462 cites W2089241151 @default.
• W2039069462 cites W2117084081 @default.
• W2039069462 cites W2122519905 @default.
• W2039069462 cites W2127563554 @default.
• W2039069462 cites W2131350133 @default.
• W2039069462 cites W2131351657 @default.
• W2039069462 cites W2137371578 @default.
• W2039069462 cites W2145204394 @default.
• W2039069462 cites W2332603886 @default.
• W2039069462 cites W2951322477 @default.
• W2039069462 cites W2952012988 @default.
• W2039069462 cites W2952306726 @default.
• W2039069462 cites W60740637 @default.
• W2039069462 doi "https://doi.org/10.1016/j.molstruc.2009.05.024" @default.
• W2039069462 hasPublicationYear "2009" @default.
• W2039069462 type Work @default.
• W2039069462 sameAs 2039069462 @default.
• W2039069462 citedByCount "6" @default.
• W2039069462 countsByYear W20390694622012 @default.
• W2039069462 countsByYear W20390694622016 @default.
• W2039069462 countsByYear W20390694622017 @default.
• W2039069462 countsByYear W20390694622018 @default.
• W2039069462 countsByYear W20390694622021 @default.
• W2039069462 crossrefType "journal-article" @default.
• W2039069462 hasAuthorship W2039069462A5005497815 @default.
• W2039069462 hasAuthorship W2039069462A5024004543 @default.
• W2039069462 hasAuthorship W2039069462A5030280190 @default.
• W2039069462 hasAuthorship W2039069462A5039779316 @default.
• W2039069462 hasAuthorship W2039069462A5074113233 @default.
• W2039069462 hasConcept C112887158 @default.
• W2039069462 hasConcept C115624301 @default.
• W2039069462 hasConcept C178790620 @default.
• W2039069462 hasConcept C185592680 @default.
• W2039069462 hasConcept C194196696 @default.
• W2039069462 hasConcept C2776568683 @default.
• W2039069462 hasConcept C2778074193 @default.
• W2039069462 hasConcept C2780874372 @default.
• W2039069462 hasConcept C2781432337 @default.
• W2039069462 hasConcept C32909587 @default.
• W2039069462 hasConcept C40869318 @default.
• W2039069462 hasConcept C544153396 @default.
• W2039069462 hasConcept C68913812 @default.
• W2039069462 hasConcept C71240020 @default.
• W2039069462 hasConcept C8010536 @default.
• W2039069462 hasConcept C92840921 @default.
• W2039069462 hasConcept C93275456 @default.
• W2039069462 hasConceptScore W2039069462C112887158 @default.
• W2039069462 hasConceptScore W2039069462C115624301 @default.
• W2039069462 hasConceptScore W2039069462C178790620 @default.
• W2039069462 hasConceptScore W2039069462C185592680 @default.
• W2039069462 hasConceptScore W2039069462C194196696 @default.
• W2039069462 hasConceptScore W2039069462C2776568683 @default.
• W2039069462 hasConceptScore W2039069462C2778074193 @default.
• W2039069462 hasConceptScore W2039069462C2780874372 @default.
• W2039069462 hasConceptScore W2039069462C2781432337 @default.
• W2039069462 hasConceptScore W2039069462C32909587 @default.

• next