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- W2039074423 abstract "Abstract The hydroformylation of 1 -pentene using the benzylidyne-capped cluster PhCCO3(CO)9 has been examined by cylindrical internal reflectance (CIR) spectroscopy. At 130°C, cluster fragmentation is observed and the formation of aldehydes is shown to coincide with fragmentation of PhCCO3(CO)9 by CIR spectroscopy. These results are discussed in relationship to the observations previously reported by Withers and Seyferth (Inorg. Chem. 22 (1983) 2931) on PhCCO3(CO)9 and its polymer-bound analogues. CIR spectral data for the CO2(CO)8-catalyzed hydroformylation of 1-pentene are also presented for comparative purposes." @default.
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- W2039074423 title "Hydroformylation catalysis explored by cylindrical internal reflectance spectroscopy. Spectroscopic evidence for the fragmentation of the benzylidyne cluster PhCCO3(CO)9" @default.
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- W2039074423 doi "https://doi.org/10.1016/0304-5102(93)e0273-j" @default.
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