Matches in SemOpenAlex for { <https://semopenalex.org/work/W2039081307> ?p ?o ?g. }
Showing items 1 to 65 of
65
with 100 items per page.
- W2039081307 endingPage "n/a" @default.
- W2039081307 startingPage "n/a" @default.
- W2039081307 abstract "Efficient molecular mixing together is a key precondition for industrial exploitation of individual macromolecules for potential product development and quality assurance with resource saving mechanism. Conceptually, MFP (melamine-formaldehyde-polyvinylpyrrolidone) polymer resin was mixed with amino acids (L-lysine, L-tyrosine, L-proline, DL-alanine), nonionic surfactants (glycerol, orcinol), iodine as metal and cationic surfactants (DTAB, TMSOI) as dispersants, in 4 : 1 ratio, w/w. A mutual molecular dispersion occurs at a cost of molecular activities with utilization of a sufficient amount of activation energies. The activation energies (Δμ*2, kJ mol−1) were derived from intrinsic viscosities ([η], kg/L) and partial molar volumes (V2, 10−6 m3/mol), which were calculated from experimental data of viscosities (η, N s m−2) and apparent molar volumes (V2, 10−6 m3/mol) of 0.005, 0.007, 0.009, and 0.0011 g/mL aqueous samples of the dispersants at 304.15 K. The limiting data were fitted to standard activation energy equations and were analyzed to assess potential of their micromixing. Densities (ρ/103 kg m−3) for apparent molar volume (V2/10−6 m3 mol−1) and viscosity (η, 0.1N, s m−2 = 0.1 kg m−1 s−1, = 1 poise, SI unit) were also measured with weight method. The Δμ*2< 0, in arrange of −48.35 to −118.03 kJ/mol were noted that inferred effective micromixing evidenced with SEM images of the blends. The Δμ*2, kJ mol−1 data are as glycerol (−118.03) > TMSOI (−117.55) > DTAB (−102.93) > orcinol (−101.54) > MFP-R (−93.71) > iodine (−59.32) > L-proline (−59.27) > L-lysine (−55.87) > DL-alanine (−55.04) > L-tyrosine (−53.04) > water (−48.35) orders with maximum utilization of Δμ*2, glycerol. © 2010 Wiley Periodicals, Inc. J Appl Polym Sci, 2010" @default.
- W2039081307 created "2016-06-24" @default.
- W2039081307 creator A5034992176 @default.
- W2039081307 creator A5063330587 @default.
- W2039081307 creator A5064986624 @default.
- W2039081307 creator A5087659271 @default.
- W2039081307 date "2010-01-01" @default.
- W2039081307 modified "2023-09-22" @default.
- W2039081307 title "Molecular activation energies (Δμ*2) of L-lysine, L-tyrosine, L-proline, DL-alanine, glycerol, orcinol, iodine, DTAB, and TMSOI for blending with melamine-formaldehyde-polyvinylpyrrolidone polymer resin illustrated with SEM" @default.
- W2039081307 cites W1965777335 @default.
- W2039081307 cites W1974624234 @default.
- W2039081307 cites W1983485394 @default.
- W2039081307 cites W1989871682 @default.
- W2039081307 cites W1994415980 @default.
- W2039081307 cites W2001519993 @default.
- W2039081307 cites W2019405769 @default.
- W2039081307 cites W2061335629 @default.
- W2039081307 cites W2070832478 @default.
- W2039081307 cites W2102830094 @default.
- W2039081307 doi "https://doi.org/10.1002/app.32457" @default.
- W2039081307 hasPublicationYear "2010" @default.
- W2039081307 type Work @default.
- W2039081307 sameAs 2039081307 @default.
- W2039081307 citedByCount "1" @default.
- W2039081307 countsByYear W20390813072022 @default.
- W2039081307 crossrefType "journal-article" @default.
- W2039081307 hasAuthorship W2039081307A5034992176 @default.
- W2039081307 hasAuthorship W2039081307A5063330587 @default.
- W2039081307 hasAuthorship W2039081307A5064986624 @default.
- W2039081307 hasAuthorship W2039081307A5087659271 @default.
- W2039081307 hasConcept C13965031 @default.
- W2039081307 hasConcept C178790620 @default.
- W2039081307 hasConcept C185592680 @default.
- W2039081307 hasConcept C188027245 @default.
- W2039081307 hasConcept C196503311 @default.
- W2039081307 hasConcept C2775930285 @default.
- W2039081307 hasConcept C2780077769 @default.
- W2039081307 hasConcept C521977710 @default.
- W2039081307 hasConceptScore W2039081307C13965031 @default.
- W2039081307 hasConceptScore W2039081307C178790620 @default.
- W2039081307 hasConceptScore W2039081307C185592680 @default.
- W2039081307 hasConceptScore W2039081307C188027245 @default.
- W2039081307 hasConceptScore W2039081307C196503311 @default.
- W2039081307 hasConceptScore W2039081307C2775930285 @default.
- W2039081307 hasConceptScore W2039081307C2780077769 @default.
- W2039081307 hasConceptScore W2039081307C521977710 @default.
- W2039081307 hasLocation W20390813071 @default.
- W2039081307 hasOpenAccess W2039081307 @default.
- W2039081307 hasPrimaryLocation W20390813071 @default.
- W2039081307 hasRelatedWork W1986974960 @default.
- W2039081307 hasRelatedWork W2043757586 @default.
- W2039081307 hasRelatedWork W2081219201 @default.
- W2039081307 hasRelatedWork W2084701745 @default.
- W2039081307 hasRelatedWork W2089511639 @default.
- W2039081307 hasRelatedWork W2604662488 @default.
- W2039081307 hasRelatedWork W2949213123 @default.
- W2039081307 hasRelatedWork W2950948582 @default.
- W2039081307 hasRelatedWork W2952544533 @default.
- W2039081307 hasRelatedWork W2953178150 @default.
- W2039081307 isParatext "false" @default.
- W2039081307 isRetracted "false" @default.
- W2039081307 magId "2039081307" @default.
- W2039081307 workType "article" @default.