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• W2039090849 abstract "The dynamics of the photochemical phase transition process of guest/host liquid crystals (LCs) containing an azobenzene derivative as a photosensitive chromophore was studied. We proposed a model for the photochemical phase transition of the guest/host LCs and simulated the change in transmittance through LCs due to the phase transition on the basis of this model. Upon irradiation at 366 nm, the cis isomer was generated randomly in the irradiated site, and then the transmittance of the probe light was slightly decreased because of the disturbance of the alignment of the nematic (N) phase by the cis isomers. Upon further irradiation, the N-to-isotropic (I) phase transition took place in local domains, and the transmittance of the probe light decreased with the growth of these local I domains. In the simulations, three factors were found to affect significantly the dynamics of the photochemical phase transition and the change in transmittance of light: the number of I domains formed by irradiation, the growth rate of the I domains, and the threshold size of the I domains detected with the probe light." @default.
• W2039090849 created "2016-06-24" @default.
• W2039090849 creator A5006991326 @default.
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• W2039090849 date "2001-12-15" @default.
• W2039090849 modified "2023-09-24" @default.
• W2039090849 title "Dynamics of Photochemical Phase Transition of Guest/Host Liquid Crystals with an Azobenzene Derivative as a Photoresponsive Chromophore" @default.
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• W2039090849 doi "https://doi.org/10.1021/cm010729m" @default.
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