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- W2039090882 abstract "Abstract The basic differential equation that describes the passage of exchanging solute through a chromatographic column is derived from a material balance on a differential element of the column by assuming that the size of the differential volume element cannot be made arbitrarily small, due to the non-homogeneity of the system. This approach is used to derive an expression for the axial diffusion coefficient which is equivalent to the experimentally determined form of the axial diffusion coefficient. The model of Fricke for conductivity in suspensions is used to relate the effective molecular diffusivity portion of the axial diffusion coefficient to the solute diffusivities in the mobile and stationary phases. This leads to a labyrinth factor for molecular diffusion in the bed that is solely a function of the void fraction." @default.
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- W2039090882 date "1973-12-01" @default.
- W2039090882 modified "2023-09-26" @default.
- W2039090882 title "A theoretical derivation of the axial diffusion coefficient in chromatography" @default.
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