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• W2039111521 startingPage "6285" @default.
• W2039111521 abstract "The self-association of penicillin V in aqueous solution at 298.15 K has been examined by conductivity, density, ultrasound, static light scattering, and microcalorimetry techniques. Two critical concentrations were detected in conductivity, light scattering, and ultrasound data over the concentration range 0−0.35 mol kg-1. Light scattering measurements indicate the formation of trimers at the first critical concentration (0.04 mol kg-1) and subsequent formation of aggregates of aggregation number 12 at the second critical concentration (0.23 mol kg-1). Analysis of the apparent molar volumes and isentropic apparent molar compressibilities has also provided evidence for limited association at concentrations below the first critical concentration. A model of the association process and possible structures of the primary and secondary aggregates have been proposed on the basis of an analysis of the thermodynamics of the self-association." @default.
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• W2039111521 date "1999-07-09" @default.
• W2039111521 modified "2023-10-16" @default.
• W2039111521 title "Self-Association of Penicillin V in Aqueous Solution" @default.
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• W2039111521 doi "https://doi.org/10.1021/la990177a" @default.
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