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- W2039114472 abstract "Thermodynamics of glycerol partial oxidation for hydrogen production has been studied by Gibbs free energy minimization method. The optimum conditions for hydrogen production are identified: reaction temperatures between 1000 and 1100 K and oxygen-to-glycerol molar ratios of 0.4–0.6 at 1 atm. Under the optimal conditions, complete conversion of glycerol, 78.93%–87.31% yield of hydrogen and 75.12%–87.97% yield of carbon monoxide could be achieved in the absence of carbon formation. The glycerol partial oxidation with O2 is suitable for providing hydrogen-rich fuels for Molten Carbonate Fuel Cell and Solid Oxide Fuel Cell. The carbon-formed and carbon-free regions are found, which are useful in guiding the search for suitable catalysts for the reaction. Inert gases have a positive effect on the hydrogen and carbon monoxide yields." @default.
- W2039114472 created "2016-06-24" @default.
- W2039114472 creator A5010709242 @default.
- W2039114472 date "2010-11-01" @default.
- W2039114472 modified "2023-10-17" @default.
- W2039114472 title "Thermodynamic analysis of glycerol partial oxidation for hydrogen production" @default.
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- W2039114472 doi "https://doi.org/10.1016/j.fuproc.2010.05.013" @default.
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