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• W2039122008 abstract "Arrhenius parameters have been measured for the abstraction of hydrogen from the C Si, Ge, and Sn tetramethyls: The rate constants correlate with the proton chemical shift, which is related to a polar effect. In all cases except carbon, a hot-molecule β-fluorine rearrangement-elimination reaction occurs following radical combination: We suggest the occurrence of a radical exchange reaction for the Si, Sn, and Ge systems, with kexchange (CF3 + Sn(Me)4) ∼ 107 ml m−1 s−1." @default.
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• W2039122008 date "1970-07-01" @default.
• W2039122008 modified "2023-09-23" @default.
• W2039122008 title "Reaction of CF3 radicals with group IV tetramethyls" @default.
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• W2039122008 doi "https://doi.org/10.1002/kin.550020405" @default.
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