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- W2039140211 abstract "The reactions of CH3COOH and CH3CHO with oxygen adsorbed on a Ag(110) surface were examined by temperature-programmed reaction spectroscopy. Acetic acid reacted with surface oxygen to form H2O plus a stable acetate intermediate. Acetaldehyde reacted with surface oxygen to form CH3CHO2(ad) which decomposed at 250 K to liberate H2 and produce the stable acetate. The role of adsorbed oxygen in these two reactions was that of a strong base and strong nucleophile, respectively. The acetate intermediates formed by these two pathways were indistinguishable. The acetate intermediate decomposed near 640 K to produce CO2, CH3COOH, CH4, and H2CCO (and deposit small amounts of surface carbon)." @default.
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- W2039140211 date "1981-01-01" @default.
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- W2039140211 title "Formation and decomposition of acetate intermediates on the Ag(110) surface" @default.
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- W2039140211 doi "https://doi.org/10.1016/0021-9517(81)90266-9" @default.
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