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- W2039147067 abstract "Pyrazole and benzotriazole-containing thioethers, namely 1,5-bis(3,5-dimethylpyrazol-1-yl)-3-thiapentane, 1,8-bis(3,5-dimethylpyrazol-1-yl)-3,6-dithiaoctane and 1,3-bis(1,2,3-benzotriazol-1-yl)-2-thiapropane were prepared and fully characterized. Oxidation of the pyrazole-containing thioether by hydrogen peroxide proceeds selectively to provide a sulfoxide or sulfone, depending on the amount of oxidant used. Oxidation of the benzotriazole derivative by hydrogen peroxide is not selective, and sulfoxide and sulfone form concurrently. Selenium dioxide-catalyzed oxidation of benzotriazole thioether by H 2 O 2 , however, proceeds selectively and yields sulfoxide only." @default.
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- W2039147067 date "2011-11-16" @default.
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- W2039147067 title "Synthesis and oxidation of some azole-containing thioethers" @default.
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- W2039147067 doi "https://doi.org/10.3762/bjoc.7.179" @default.
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