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- W2039174734 abstract "Dehydroesterification of iso and cycloalkanes has been carried out with methyl formate and H2SO4 at atmospheric pressure slightly above room temperature. The yields range from 32 to 70%. The reaction takes place at tertiary carbon; no fragmentation of the hydrocarbon skeleton is observed. The reaction fails with normal alkanes. The effect of reaction conditions is discussed. A mechanism involving an hydride transfer for the activation of the alkane is given. The reaction is extended to other alkyl formates." @default.
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- W2039174734 date "1995-01-01" @default.
- W2039174734 modified "2023-10-16" @default.
- W2039174734 title "Preparation of unsaturated carboxylic acid esters with metallosilicate catalysts" @default.
- W2039174734 doi "https://doi.org/10.1016/0144-2449(95)90258-9" @default.
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