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- W2039244401 abstract "A rare gold(I) ethylene complex and the closely related copper(I) ethylene adduct have been isolated using [N{(C3F7)C(2,6-Cl2C6H3)N}2]− as the supporting ligand. [N{(C3F7)C(2,6-Cl2C6H3)N}2]Au(C2H4) (1) is an air-stable solid. It features a U-shaped triazapentadienyl ligand backbone and a three-coordinate, trigonal-planar gold center. The copper(I) adduct [N{(C3F7)C(2,6-Cl2C6H3)N}2]Cu(C2H4) (2) also has a similar structure. The 13C NMR signal corresponding to the ethylene carbons of 1 appears at about 64 ppm upfield from the free ethylene, while the ethylene carbons of 2 show a relatively smaller (39 ppm) upfield shift. [N{(C3F7)C(2,6-Cl2C6H3)N}2]M(C2H4) (M = Cu, Au) mediate carbene-transfer reactions from ethyl diazoacetate to saturated and unsaturated hydrocarbons." @default.
- W2039244401 created "2016-06-24" @default.
- W2039244401 creator A5027770988 @default.
- W2039244401 creator A5076417394 @default.
- W2039244401 date "2008-04-23" @default.
- W2039244401 modified "2023-10-12" @default.
- W2039244401 title "Gold(I) Ethylene and Copper(I) Ethylene Complexes Supported by a Polyhalogenated Triazapentadienyl Ligand" @default.
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- W2039244401 doi "https://doi.org/10.1021/ic800373u" @default.
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