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- W2039267533 abstract "Random multiblock polyamide-polyether copolymers containing 13–30 wt% of polyether have been synthesized by a two-step procedure from adipoyl chloride, 1,6-diaminohexane and two α,ω-dihydroxy-poly(ethylene oxides) having M̄n=600 and 1550 g mol−1. The compositions and architectures of the copolymers were determined by elemental analysis and by 1H nuclear magnetic resonance spectroscopy. Thermal analysis showed the presence of a main crystalline component that thermal parameters indicated as polyamidic. Transport properties were analysed using water vapour as permeant; they indicated a permeability much higher than in polyamide-6,6 and suggested the presence in the amorphous component of a domain structure in which polyether volume elements are segregated from a polyamide matrix. Thermomechanical and dynamic mechanical analyses suggested that flexible polyether sequences increase the overall flexibility of the copolymer chains." @default.
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- W2039267533 date "1986-05-01" @default.
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- W2039267533 title "Synthesis and physical behaviour of poly(amidoether) block copolymers" @default.
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- W2039267533 doi "https://doi.org/10.1016/0032-3861(86)90141-2" @default.
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