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- W2039276247 abstract "The diastereomerization of η3-allylpalladium chloride complexes (I–III) of the phosphines 4,4-dimethyl-t-6-methyl-t-2,r-3-diphenyl-1,3-oxaphosphorinane (1), o-bromobenzylphenylmethylphosphine (2) 1-phosphabicyclo[3.2.1]octane (3) has been studied by two-dimensional 1H NMR spectroscopy. Two processes are distinguished: a faster process, η3 ⇌ η1-conversion combined with a preferred CC-rotation (α-mechanism), and a slower process, η3 ⇌ η1-conversion combined with CC-rotation and CPd-rotation (γ-mechanism). In complexes containing bulky phosphines both processes are retarded." @default.
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- W2039276247 date "1984-07-01" @default.
- W2039276247 modified "2023-10-16" @default.
- W2039276247 title "Intramolecular mobility of η3-allylpalladium chloride complexes of different phosphines studied by two dimensional NMR spectroscopy" @default.
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- W2039276247 doi "https://doi.org/10.1016/0022-328x(84)80298-3" @default.
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