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• W2039276713 abstract "Selective synthesis of 1,2,4,5-tetrasubstituted benzenes was achieved via formation of 2,5-bis(trimethylsilyl)zirconacyclopentadienes from 2 equiv of TMS-substituted alkynes with Cp(2)ZrBu(2) and Cu-mediated formation of 1,4-disilylbenzene by cycloaddition of zirconacyclopentadienes to disubstituted alkynes. Preparation of 1,2,3,4,9,10-hexasubstituted pentacene and 2,3,6,11-tetrasubstituted naphthacene derivatives were demonstrated by a homologation or coupling method using tetrasubstituted benzene." @default.
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• W2039276713 date "2009-07-08" @default.
• W2039276713 modified "2023-10-05" @default.
• W2039276713 title "Zirconium-Mediated Selective Synthesis of 1,2,4,5-Tetrasubstituted Benzenes from Two Silyl-Substituted Alkynes and One Internal Alkyne" @default.
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• W2039276713 doi "https://doi.org/10.1021/ol901153p" @default.
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