FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2039314721> ?p ?o ?g. }

• W2039314721 endingPage "161" @default.
• W2039314721 startingPage "156" @default.
• W2039314721 abstract "A laser flash photolysis–resonance fluorescence technique has been employed to investigate the kinetics of the reaction of ground state oxygen atoms, O(3PJ), with (CH3)2SO (dimethylsulfoxide) as a function of temperature (266–383 K) and pressure (20–100 Torr N2). The rate coefficient (kR1) for the O(3PJ) + (CH3)2SO reaction is found to be independent of pressure and to increase with decreasing temperature. The following Arrhenius expression adequately describes the observed temperature dependence: kR1(T) = (1.68 ± 0.76) × 10−12 exp[(445 ± 141)/T] cm3 molecule−1 s−1, where the uncertainties in Arrhenius parameters are 2σ and represent precision only. The absolute accuracy of each measured rate coefficient is estimated to be ±30%, and is limited predominantly by the uncertainties in measured (CH3)2SO concentrations. The observed temperature and pressure dependencies suggest that, as in the case of O(3PJ) reactions with CH3SH and (CH3)2S, reaction occurs by addition of O(3PJ) to the sulfur atom followed by rapid fragmentation of the energized adduct to products. The O(3PJ) + (CH3)2SO reaction is fast enough so that it could be a useful laboratory source of the CH3SO2 radical if this species is produced in significant yield. © 2002 Wiley Periodicals, Inc. Int J Chem Kinet 34: 156–161, 2002; DOI 10.1002/kin.10040" @default.
• W2039314721 created "2016-06-24" @default.
• W2039314721 creator A5058836825 @default.
• W2039314721 creator A5069190222 @default.
• W2039314721 creator A5069853551 @default.
• W2039314721 date "2002-02-07" @default.
• W2039314721 modified "2023-10-18" @default.
• W2039314721 title "A temperature-dependent kinetics study of the reaction of O(3PJ) with (CH3)2SO" @default.
• W2039314721 cites W1603395937 @default.
• W2039314721 cites W1967804366 @default.
• W2039314721 cites W1977426614 @default.
• W2039314721 cites W1987616537 @default.
• W2039314721 cites W1992126464 @default.
• W2039314721 cites W2001664973 @default.
• W2039314721 cites W2004666275 @default.
• W2039314721 cites W2015988075 @default.
• W2039314721 cites W2023283805 @default.
• W2039314721 cites W2039695211 @default.
• W2039314721 cites W2043982119 @default.
• W2039314721 cites W2059371280 @default.
• W2039314721 cites W2063922606 @default.
• W2039314721 cites W2074918848 @default.
• W2039314721 cites W2077365954 @default.
• W2039314721 cites W2077959466 @default.
• W2039314721 cites W2089865251 @default.
• W2039314721 cites W2090443314 @default.
• W2039314721 cites W2090859074 @default.
• W2039314721 cites W2146830635 @default.
• W2039314721 cites W2322165531 @default.
• W2039314721 cites W2949271369 @default.
• W2039314721 cites W3157022837 @default.
• W2039314721 doi "https://doi.org/10.1002/kin.10040" @default.
• W2039314721 hasPublicationYear "2002" @default.
• W2039314721 type Work @default.
• W2039314721 sameAs 2039314721 @default.
• W2039314721 citedByCount "5" @default.
• W2039314721 countsByYear W20393147212012 @default.
• W2039314721 crossrefType "journal-article" @default.
• W2039314721 hasAuthorship W2039314721A5058836825 @default.
• W2039314721 hasAuthorship W2039314721A5069190222 @default.
• W2039314721 hasAuthorship W2039314721A5069853551 @default.
• W2039314721 hasConcept C108204754 @default.
• W2039314721 hasConcept C113196181 @default.
• W2039314721 hasConcept C121332964 @default.
• W2039314721 hasConcept C13472781 @default.
• W2039314721 hasConcept C147789679 @default.
• W2039314721 hasConcept C148898269 @default.
• W2039314721 hasConcept C161790260 @default.
• W2039314721 hasConcept C175113610 @default.
• W2039314721 hasConcept C178790620 @default.
• W2039314721 hasConcept C185592680 @default.
• W2039314721 hasConcept C30646810 @default.
• W2039314721 hasConcept C36663273 @default.
• W2039314721 hasConcept C44740213 @default.
• W2039314721 hasConcept C54582936 @default.
• W2039314721 hasConcept C62520636 @default.
• W2039314721 hasConcept C75473681 @default.
• W2039314721 hasConcept C86183883 @default.
• W2039314721 hasConcept C93391505 @default.
• W2039314721 hasConcept C95121573 @default.
• W2039314721 hasConcept C97355855 @default.
• W2039314721 hasConceptScore W2039314721C108204754 @default.
• W2039314721 hasConceptScore W2039314721C113196181 @default.
• W2039314721 hasConceptScore W2039314721C121332964 @default.
• W2039314721 hasConceptScore W2039314721C13472781 @default.
• W2039314721 hasConceptScore W2039314721C147789679 @default.
• W2039314721 hasConceptScore W2039314721C148898269 @default.
• W2039314721 hasConceptScore W2039314721C161790260 @default.
• W2039314721 hasConceptScore W2039314721C175113610 @default.
• W2039314721 hasConceptScore W2039314721C178790620 @default.
• W2039314721 hasConceptScore W2039314721C185592680 @default.
• W2039314721 hasConceptScore W2039314721C30646810 @default.
• W2039314721 hasConceptScore W2039314721C36663273 @default.
• W2039314721 hasConceptScore W2039314721C44740213 @default.
• W2039314721 hasConceptScore W2039314721C54582936 @default.
• W2039314721 hasConceptScore W2039314721C62520636 @default.
• W2039314721 hasConceptScore W2039314721C75473681 @default.
• W2039314721 hasConceptScore W2039314721C86183883 @default.
• W2039314721 hasConceptScore W2039314721C93391505 @default.
• W2039314721 hasConceptScore W2039314721C95121573 @default.
• W2039314721 hasConceptScore W2039314721C97355855 @default.
• W2039314721 hasIssue "3" @default.
• W2039314721 hasLocation W20393147211 @default.
• W2039314721 hasOpenAccess W2039314721 @default.
• W2039314721 hasPrimaryLocation W20393147211 @default.
• W2039314721 hasRelatedWork W1999422702 @default.
• W2039314721 hasRelatedWork W1999474704 @default.
• W2039314721 hasRelatedWork W2040234844 @default.
• W2039314721 hasRelatedWork W2040870860 @default.
• W2039314721 hasRelatedWork W2043801619 @default.
• W2039314721 hasRelatedWork W2083699664 @default.
• W2039314721 hasRelatedWork W2093109851 @default.
• W2039314721 hasRelatedWork W2117509483 @default.
• W2039314721 hasRelatedWork W29277387 @default.
• W2039314721 hasRelatedWork W4235863808 @default.
• W2039314721 hasVolume "34" @default.
• W2039314721 isParatext "false" @default.
• W2039314721 isRetracted "false" @default.

• next