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- W2039335997 abstract "Abstract Distribution coefficients of metal acetylacetonates such as Al(acac) 3 , Cr(acac) 3 and Co(acac) 3 etc., and n-alkanes in porous polystyrene gel chromatography with ten organic solvents as eluants were estimated and compared with those obtained by the batch method in two solvent systems. Solubility parameters of the metal acetylacetonates were determined. There is a relationship between the distribution coefficients and solubility parameters of solutes and solvents. Two factors (steric exclusion and partition) play important roles in each solvent for the separation mechanisms of the present systems. The latter factor was estimated successfully from a regular solutions approximation." @default.
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- W2039335997 date "1976-12-01" @default.
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- W2039335997 title "Solvent effects in gel chromatography: the relationship between the distribution coefficients of metal acetylacetonates and solubility parameters of solvents" @default.
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- W2039335997 doi "https://doi.org/10.1016/s0003-2670(01)82266-2" @default.
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