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- W2039343455 abstract "Abstract Photochemical and anionic polymerizations of 1,2-diaza-1,3-butadienes are described. Photochemical polymerization was smoothly performed by irradiation of some 1-aminocarbonyl-1,2-diaza-1,3-butadienes with high pressure mercury arc ( λ = 300 nm) in the presence of allyltributylstannane. Molecular weights ( M w ) in the range 14.6–559 × 10 2 g/mol were obtained. The TGA curve revealed a first weight loss starting at about 200 °C of some 85%, and a second starting at about 300 °C. The DSC showed the glass transition ( T g ) at about −34 °C. Anionic polymerization was performed by treatment of some 1-alkoxycarbonyl-1,2-diaza-1,3-butadienes with n -butyllithium. Molecular weights ( M w ) in the range 8.44–242 × 10 2 g/mol were obtained." @default.
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- W2039343455 date "2008-08-01" @default.
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- W2039343455 title "Synthesis of new polyazines by 1,4 photochemical or anionic polymerization of 1,2-diaza-1,3-butadienes" @default.
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- W2039343455 doi "https://doi.org/10.1016/j.eurpolymj.2008.06.014" @default.
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