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- W2039352431 abstract "Mid-infrared, far-infrared, and Raman spectra for Ni1−xCoxOy indicated the systematic variation from a spinel-type (x=1.0) to an inverse spinel-type (x=0.67) lattice, through a multiphase transition region, to an NaCl-type (x<0.25) structure. Further analysis reveals that a decrease in x in this system is accompanied by the formation of octahedral/Ni2+, which, in the case of spinel compositions Ni1−xCoxO4/3 (x=0.67 to 1.0), results in substitution of Co3+ into tetrahedral sites and/or the redistribution of charge around some of the oxygen ions. The proposed transition region explains the observed break in continuity, at around x=0.5, in the previously reported resistivity data for nickel cobalt oxide films." @default.
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- W2039352431 date "2004-05-15" @default.
- W2039352431 modified "2023-10-10" @default.
- W2039352431 title "Vibrational spectroscopic study of the site occupancy distribution of cations in nickel cobalt oxides" @default.
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- W2039352431 doi "https://doi.org/10.1063/1.1699505" @default.
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