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- W2039383721 abstract "Summary A study has been made of the electrical double layer on silver iodide in water-ethylene glycol mixtures (0–100%). The replacement of water by ethylene glycol has the following consequences: (a) The solubility of silver iodide increases by about a factor of two. (b) The point of zero charge moves in a positive direction; this is in a minor part attributable to a change in solvation free energy of the Ag+- and I−-ions and to a large extent to a change in χ-potential—the maximum shift is +64.5 mV. (c) The double layer capacitance decreases. This is due to a decrease of e′/4πd. However, there is also some increase in specific adsorption. (d) All curves pass through a common intersection point located at −3.3 to −3.8 μC cm−2, depending on the nature of the counterion. This point can be identified as the surface charge where the relative surface excess of ethylene glycol is maximal. Comparison of the double layer properties on silver iodide with those on mercury as measured by Trasatti reveal qualitative similarities as well as quantitative differences." @default.
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- W2039383721 date "1973-01-01" @default.
- W2039383721 modified "2023-09-23" @default.
- W2039383721 title "The electrical double layer on silver iodide in water-ethylene glycol mixtures" @default.
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- W2039383721 doi "https://doi.org/10.1016/s0022-0728(73)80442-5" @default.
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