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- W2039403666 abstract "Abstract The uns-cis-[Cr(1,3-pdda)(L)]− complexes (1,3- pdda = 1,3-propanediamine-N,N′-diacetate; L = oxalate or malonate) were prepared and resolved. The corresponding s-cis-[Cr(edda)L]− complexes (edda = ethylenediamine-N,N′-diacetate) have been partially resolved. The infrared absorption and circular dichroism (CD) spectra are reported. Rotational strengths of the uns-cis-[Cr(1,3-pdda)(L)]− complexes decrease with increasing chelate ring size of the bidentate anionic ligands. (−)589-[Co(en)2- (C2O4)]uns-cis-(−)546-[Cr(1,3-pdda)(mal)]·H2O crystallizes in the space group P21 of the monoclinic crystal system with a = 7.832(3), b = 14.207(6), c = 10.801(3) A, β = 98.46(3)° and Z = 2. In the anionic chromium complex, the six-membered diamine ring assumes the stable chair conformation; the equatorial glycinate ring is puckered; and the axial glycinate ring is in the ‘envelope’ conformation. The absolute configuration of the chromium complex ion is ΔΔΔΛ." @default.
- W2039403666 created "2016-06-24" @default.
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- W2039403666 date "1989-03-01" @default.
- W2039403666 modified "2023-10-11" @default.
- W2039403666 title "Diamine-N,N′-diacetatochromate(III) complexes with oxalate and malonate anions. Crystal structure of (−)589-[Co(en)2(C2O4)](−)546-[Cr(1,3-pdda)(mal)]·H2O" @default.
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- W2039403666 doi "https://doi.org/10.1016/s0020-1693(00)83420-9" @default.
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