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• W2039408832 abstract "The reactions of the organic-soluble (trimethylsilyl)arylaminosilanetriol RSi(OH)3 (R = (2,6-i-Pr2C6H3)NSiMe3) (1) with titanocene dichloride and zirconocene dichloride in dimethoxyethane as the solvent leads to the formation of acyclic and cyclic siloxanes [RSi(OH)2(OTiCp2Cl)] (2) and [RSi(OH)(OZrCp2)O]2 (3), respectively. The molecular structures of the new products 2 and 3 have been established by means of their analytical and spectral data. Further, in each case the solid-state structure of the compounds has been determined by single crystal X-ray diffraction studies. The EI mass spectral data reveal the presence of higher molecular weight compounds in the gas phase corresponding to the bicyclic or cubic structures of 2 and 3, respectively." @default.
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• W2039408832 date "1997-12-01" @default.
• W2039408832 modified "2023-10-17" @default.
• W2039408832 title "Syntheses, spectroscopy and crystal structures of new group 4 metallasiloxanes" @default.
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• W2039408832 doi "https://doi.org/10.1016/s0022-2860(97)00222-6" @default.
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