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• W2039431133 abstract "Both a C1 and a C18 saturated hydrocarbon have been bonded to 75-μm capillaries for high-voltage capillary electrophoresis separations. The performance of these bonded phases has been compared with unbonded capillaries under a variety of experimental conditions. The bonded phases were prepared by a flow-through procedure at room temperature, and the reproducibilities of the electroosmotic flow for the C1 and C18 capillaries were 6 and 3%, respectively. Both of the bonded phases reduced interactions between the silica surface and positively charged ions, but for larger hydrophobic ions sorption and peak tailing were observed on the C18 phase. In the presence of sodium dodecylsulfate and sodium decanesulfonate it was possible to control the electroosmotic flow over a wide range. The separation of lanthanide metal ions is illustrated, and improved resolution and reduced surface interactions are shown for the bonded phases." @default.
• W2039431133 created "2016-06-24" @default.
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• W2039431133 date "1992-06-01" @default.
• W2039431133 modified "2023-09-23" @default.
• W2039431133 title "Bonded-phase capillaries and the separation of inorganic ions by high-voltage capillary electrophoresis" @default.
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• W2039431133 doi "https://doi.org/10.1016/0021-9673(92)80085-9" @default.
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