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- W2039458373 abstract "Abstract The carbonylation in toluene of 2-nitrochalcones at 20 bar and 100°C, with Pd(TMB) 2 as catalyst and TMPhen as cocatalyst (TMBH = 2,4,6-trimethyl benzoic acid; TMPhen = 3,4,7,8-tetramethyl-1,10-phenanthroline) gave the corresponding 2-acyl indoles in 60–98% yields. The use as catalyst of Ru 3 (CO) 12 activated by a rigid α-diimine ligand such as DIAN-Me(∗), in ethanol-water, at 30 bar and 170°C, gave a mixture of the corresponding acyl indoles and quinolines, the latter being usually the most abundant products." @default.
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- W2039458373 date "1996-09-01" @default.
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- W2039458373 title "Intramolecular amination catalysed by ruthenium and palladium. Synthesis of 2-acyl indoles and 2-aryl quinolines by carbonylation of 2-nitrochalcones" @default.
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