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- W2039505526 abstract "The crystallization of offretite at 110°C from reaction mixtures with the composition 6.2 (aK + bNa + x TMA)2 O; Al2O3; 15.3SiO2; 280H2O has been studied as a function of x and b(a + b). When x ≧ 0.3 mixtures of offretite and sodalite are produced after 72 h of reaction and pure sodalite is obtained after eight days. When x = 0.04 up to 75% of the potassium ions can be replaced by sodium to produce pure offretite. Increasing the sodium fraction in the parent synthesis mixtures increases both the rates of nucleation and crystal growth, reduces the silica content of the crystals and changes the final size and morphology of the crystallites. The results are consistent with a solution phase crystallization mechanism in which the concentration in dissolved species is increased by the presence of sodium ions." @default.
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- W2039505526 date "1987-01-01" @default.
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- W2039505526 title "Influence of sodium ions in the synthesis of offretite" @default.
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- W2039505526 doi "https://doi.org/10.1016/0144-2449(87)90122-9" @default.
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