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- W2039561310 abstract "The oxidation of n-butene-1 was carried out in a stirred tank reactor and in a pulse reactor using MnMoO4 as a catalyst. This catalyst exhibits a fairly good selectivity to maleic anhydride. MnMoO4 shows a polyfunctional nature; it is possible to distinguish the properties of isomerization, dehydrogenation, oxidation with oxygen insertion, and complete oxidation by varying parameters such as temperature, oxygen concentration and contact time. The compositions of the products in the oxidation of n-butene-1 carried out in a pulse reactor are completely different in the presence and in the absence of oxygen, respectively. In the absence of oxygen, MnMoO4 is a very selective catalyst in the dehydrogenation of n-butene-1 to butadiene. In the presence of oxygen, CO and CO2 are the main products together with small amounts of maleic anhydride. The selectivity of MnMoO4 to butadiene formation has been attributed to the presence of MoO bonds which are responsible for dehydrogenation reactions. A monocenter oxidation mechanism, accounting for the formation of CO, CO2, and maleic anhydride, has been proposed in which the gaseous oxygen is considered to be adsorbed on the same center of the hydrocarbon." @default.
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- W2039561310 date "1973-09-01" @default.
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- W2039561310 title "Oxidation of butenes to maleic anhydride on MnMoO4 based catalyst*1" @default.
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