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• W2039571723 abstract "Iron and copper complexes of tetraphenyl-m-benziporphyrin (TPmBPH)H have been prepared and structurally characterized. The iron system, (TPmBPH)FeIIBr, contains a high-spin Fe(II) center. In the solid state the complex forms dimeric units linked by weak CH···Br hydrogen bonds. The Cu complex contains a tetrameric copper cluster with a Cu2Cl42- unit bridging two [(TPmBPCl)CuII]+ fragments. The formation of (TPmBPCl)H represents an example of copper-catalyzed chlorination on the internal carbon atom of (TPmBPH)H." @default.
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• W2039571723 date "2004-06-05" @default.
• W2039571723 modified "2023-10-14" @default.
• W2039571723 title "Iron and Copper Complexes of Tetraphenyl-<i>m</i>-benziporphyrin: Reactivity of the Internal C−H Bond" @default.
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• W2039571723 doi "https://doi.org/10.1021/ic049821l" @default.
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