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- W2039589020 abstract "Laser selective excitation, fluorescence line narrowing, and excited state absorption techniques have been used to investigate the electronic-energy-level structure of the 5f7 ion Cm3+ in the host crystal LuPO4. Crystal-field levels have been determined up to 35 700 cm−1 for the principal D2d symmetry site. Eighty levels have been assigned and fitted to a parametric Hamiltonian with an rms deviation of 28.4 cm−1. Inhomogeneous broadening of the electronic transitions and the small 9.5 cm−1 splitting of the nominally 8S7/2 ground multiplet are responsible for satellite lines reported previously. Time resolved fluorescence line narrowing was used to observe energy transfer between different subsites of the intrinsic Cm3+ center. It was found that electric-dipole interactions mediate this energy transfer." @default.
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- W2039589020 date "1996-08-15" @default.
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- W2039589020 title "Excited state absorption and fluorescence line narrowing studies of Cm<sup>3+</sup> in LuPO<sub>4</sub>" @default.
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- W2039589020 doi "https://doi.org/10.1063/1.472118" @default.
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