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• W2039595183 abstract "The blends of isotactic polypropylene (iPP) and poly(butylene terephthalate) (PBT) were prepared by using a special injection molding process named oscillation shear injection molding (OSIM). Morphology, crystallization behavior and molecular orientation were investigated systematically. The Scanning Electronic Microscopy (SEM) results showed that the dispersed PBT phase changed from sphere to fibril-like morphology in shear layer, due to the shear stress imposed during the packing stage. The interfacial adhesion of two phases could be enhanced by applying shear stress and could be further strengthened by the addition of compatibilizer. The crystallization behavior was investigated by the Differential Scanning Calorimetry (DSC). iPP/PBT blends showed higher onset crystallization temperature (To) and peak crystallization temperature (TP) than neat iPP, indicating that PBT phase can serve as a good heterogeneous nucleation agent for iPP crystallization. Moreover, the two-dimensional wide angle X-ray diffraction (2D-WAXD) revealed that the deformed PBT phase could cause iPP molecules around them to retain the orientation or to slow down the relaxation of iPP chains, and PBT phase facilitated the formation of α-iPP." @default.
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• W2039595183 date "2012-03-01" @default.
• W2039595183 modified "2023-10-06" @default.
• W2039595183 title "Morphology and Crystallization Behavior of Compatibilized Isotactic Polypropylene/Poly(butylene terephthalate) Blends under Shear Flow" @default.
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• W2039595183 doi "https://doi.org/10.1080/03602559.2011.651248" @default.
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