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- W2039608253 abstract "Carbon−carbon sigma-bond activation is a contemporary challenge for organometallic chemistry and catalysis. Herein, we disclose a new alkene carboacylation reaction initiated by quinoline-directed, rhodium-catalyzed C−C σ bond activation. The alkene carboacylation allows for the construction of all-carbon quaternary centers, with a broad substrate scope, providing access to carbocyclic and heterocyclic ring systems in good to excellent yields." @default.
- W2039608253 created "2016-06-24" @default.
- W2039608253 creator A5082089241 @default.
- W2039608253 creator A5087408273 @default.
- W2039608253 date "2008-12-23" @default.
- W2039608253 modified "2023-10-03" @default.
- W2039608253 title "Catalytic Carbon−Carbon σ Bond Activation: An Intramolecular Carbo-Acylation Reaction with Acylquinolines" @default.
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- W2039608253 doi "https://doi.org/10.1021/ja8066308" @default.
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