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• W2039608913 endingPage "128" @default.
• W2039608913 startingPage "122" @default.
• W2039608913 abstract "Four coordination polymers, namely, {[Co(μ-glu)(nmim)2]·2H2O}n (1), [Cu(μ-glu)(nmim)2]n (2), {[Zn(μ-glu)(nmim)2]·2H2O}n (3) and [Cd(μ-glu)(nmim)2] (4) (glu = glutarate, nmim = N-methylimidazole), have been synthesized and characterized by elemental analysis, IR spectroscopy, thermal analysis and single-crystal X-ray diffraction techniques. Moreover, the photoluminescence properties of 3 and 4 have been investigated. Structural analyses reveal that all the complexes exhibit one-dimensional (1D) linear chain structures bridged by the glutarate ligand, which further form 3D supramolecular networks via intermolecular π⋯π, C–H⋯π and weak hydrogen bonding interactions. In the complexes, the glu ligand adopts the bis-monodentate and bis-bidentate bridging modes through two and four carboxylate oxygen atoms, respectively. The distorted octahedral geometry for complexes 2 and 4 and tetrahedral geometry for complexes 1 and 3 are completed by two nmim ligands. Complexes 3 and 4 exhibit a blue emission in the solid state at room temperature." @default.
• W2039608913 created "2016-06-24" @default.
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• W2039608913 date "2014-01-01" @default.
• W2039608913 modified "2023-10-16" @default.
• W2039608913 title "One-dimensional coordination polymers of copper(II), cobalt(II), zinc(II) and cadmium(II) with glutarate and N-methylimidazole" @default.
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• W2039608913 doi "https://doi.org/10.1016/j.poly.2013.08.068" @default.
• W2039608913 hasPublicationYear "2014" @default.
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