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- W2039630166 abstract "Abstract We use the generalized van der Waals theory to derive forms of the Helmholtz free energy [fbar] for orientationally ordered liquids composed of rod-like molecules. The theoretically derived density and temperature dependences of [fbar] are compared with those assumed in current phenomenological descriptions, and used to discuss the competing roles of intermolecular attractions and repulsions. Successively higher order angle dependences in the mean attraction and packing entropy contributions to [fbar] are considered. Contrary to recent suggestions from phenomenological analyses, these corrections are argued to increase the discrepancy between theoretical and measured values of the orientational order parameter, transition temperature, etc. We then present the results of computations on the thermodynamic properties of a fluid of asymmetric ellipsoidal particles, all of whose axes are different. It is concluded that the relative stability of the nematic phase, and hence the strength of the first-order phase transition, is significantly exaggerated by failing to take into account deviations from cylindrical molecular symmetry." @default.
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- W2039630166 date "1979-01-01" @default.
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- W2039630166 title "On the Form of the Free Energy for Uniaxially Ordered Liquids" @default.
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- W2039630166 doi "https://doi.org/10.1080/00268947908069803" @default.
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