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- W2039688836 abstract "Dicatechol ligands 3b–g-H4 are simply prepared by imine formation of 2,3-dihydroxybenzaldehyde 2 with a series of different diamines 1b–g. An X-ray structural analysis was obtained for the butyl-bridged compound 3e-H4, showing an intramolecular proton transfer and the formation of a chinoidic “keto-amine” structure. The dicatechol derivatives 3b–g-H4 form dinuclear triple-stranded helicates M4[(3)3Ti2] with titanium(IV) ions in the presence of alkali-metal carbonate. For the phenyl- and the trans-1,4-cyclohexyl-bridged complexes, K4[(3b)3Ti2] and Na4[(3f)3Ti2], X-ray structures were obtained." @default.
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- W2039688836 date "2004-01-01" @default.
- W2039688836 modified "2023-10-10" @default.
- W2039688836 title "Dicatechol-diimines: easily accessible ligands for the self-assembly of dinuclear triple-stranded helicates" @default.
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- W2039688836 doi "https://doi.org/10.1039/b311483j" @default.
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