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- W2039695211 abstract "The room temperature reactions between oxygen atoms and methanethiol, ethanethiol, and methylsulfide have been studied in crossed jets to directly detect and identify the free-radical and stable products they produce. Knowledge of the products was used to assign reactive routes. The overall rate constants for all three O-atom reactions were also measured at 300 ± 2°K using a fast-flow reactor. They are 1.9 (CH3SH), 2.8 (C2H5SH), and 63 (CH3SCH3) × 10−12cm3/mol · sec. The identity of the detected products and the trend in rate constants in these reactions support an electrophilic addition mechanism followed by decomposition of the excited adduct by S-R bond cleavage (R = H, CH3, or C2H5)." @default.
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- W2039695211 date "1976-05-01" @default.
- W2039695211 modified "2023-09-23" @default.
- W2039695211 title "Direct identification of reactive routes and measurement of rate constants in the reactions of oxygen atoms with methanethiol, ethanethiol, and methylsulfide" @default.
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- W2039695211 doi "https://doi.org/10.1002/kin.550080310" @default.
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