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- W2039698717 abstract "The influence of solvent on the selectivity of α-olefin in the product hydrocarbon as a function of carbon number over a 20 wt.% Co on SiO2 catalyst under the typical reaction conditions of 513 K, 4.5 MPa and H2/CO = 2 has been investigated. Hydrocarbons with different carbon numbers and molecular structures, including n-hexane, n-octane, n-decane, n-dodecane, n-hexadecane, iso-octane and decahydronaphthalene, were used as solvents. Although the selected solvents did not obviously affect the catalytic activity or chain growth probability (α-value), they exhibited remarkable influences on the α-olefin selectivity. In the case of n-hexane solvent, the α-olefin content in the product decreased markedly with increasing carbon number of the product. The n-decane solvent gave the highest olefin content. It was independent of carbon number on the C6+ product at the level of about 40%. This could be attributed to quicker desorption, diffusion and more suppressed re-adsorption of primary FTS product (α-olefin)." @default.
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- W2039698717 date "2006-04-01" @default.
- W2039698717 modified "2023-10-16" @default.
- W2039698717 title "Effects of solvent on Fischer–Tropsch synthesis" @default.
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- W2039698717 doi "https://doi.org/10.1016/j.apcata.2006.02.009" @default.
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