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- W2039700742 abstract "Preliminary enzymatic polymerization studies in the simple stoichiometric adipic acid/butane-1,4-diol system using lipase B from Candida antarctica, immobilized as Novozym 435®, suggest that in solvent-free conditions a step-growth mechanism operates involving the sequential addition of an AB synthon by esterification mode only. Conversely, in toluene as solvent there is a change to the more facile transesterification mode in line with the conventional polyesterification procedure, pointing to a change in specificity of the lipase. Evidence is drawn from qualitative studies using a series of synthetic intermediates, enabling authentication of product mixtures together with an indication of the comparative reactivity of species along the proposed reaction pathway. © 1998 John Wiley & Sons, Inc. J Polym Sci A: Polym Chem 36: 2069–2080, 1998" @default.
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- W2039700742 date "1998-09-15" @default.
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- W2039700742 title "Studies of lipase-catalyzed polyesterification of an unactivated diacid/diol system" @default.
- W2039700742 doi "https://doi.org/10.1002/(sici)1099-0518(19980915)36:12<2069::aid-pola13>3.0.co;2-4" @default.
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