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- W2039702904 abstract "The stereochemistry of the 2,5-disubstituted tetrahydrofuran formed on treating 5-methyl-1-phenylhex-4-en-1-ol [6] with thallium(III) acetate in appropriate solvents has been established as trans by means of nuclear Overhauser experiments. Replacement of the hydroxy group of [6] by ether, ester, amide or carbamate functionalities suppresses intramolecular nucleophilic participation during oxythallation. Instead, products of acetoxythallation followed by solvolysis of the C-Tl bond or by methyl group migration are isolated." @default.
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- W2039702904 date "1990-01-01" @default.
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- W2039702904 title "Heterocyclisations induced by thallium(III) acetate. Effect of varying the internal nucleophile" @default.
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- W2039702904 doi "https://doi.org/10.1016/s0040-4020(01)82035-4" @default.
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